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Free Energy of a Nonuniform System. I. Interfacial Free Energy
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Free Energy of a Nonuniform System. I. Interfacial Free Energy
John W. Cahn; J. E. Hilliard · The Journal of Chemical Physics · 1958
It is shown that the free energy of a volume V of an isotropic system of nonuniform composition or density is given by : NV∫V [f0(c)+κ(▿c)2]dV, where NV is the number of molecules per unit volume, ▿c the compositi...
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