Formation of HCO+ and HCS+ Ions in the Photodissociation of CH3OC(S)SCH3 under VUV Synchrotron Radiation

Artículo

Formation of HCO+ and HCS+ Ions in the Photodissociation of CH3OC(S)SCH3 under VUV Synchrotron Radiation

Rodriguez Pirani, Lucas Sebastian et al · American Chemical Society · 2019

Materiale supplementare disponibile

Lettura rapida. Controlla i dati essenziali della risorsa e accedi al contenuto con il pulsante principale. La scheda mostra solo le informazioni necessarie per identificare, citare e aprire l’opera.

Autore / responsabile

Rodriguez Pirani, Lucas Sebastian et al

Editore

American Chemical Society

Anno

2019

ISSN

6674-6682

ISSN

6674-6682

Lingua

Inglés

Accesso alla risorsa

Apri il contenuto dall’opzione principale o scegli un’altra fonte disponibile.

CONICET Digital CONICET Digital OAI-PMH

Entrar por CONICET Digital

Accesso principale

Materiale supplementare disponibile

El enlace apunta a material asociado, anexos, tablas, datos o página complementaria. No se marca como libro/texto completo.

Apri materiale

Riepilogo

Descripción general del contenido del recurso.

Synchrotron-based total ion yield and photoelectron-photoion-coincidence spectra have been applied to investigate the electronic structure and the dissociative ionization of gaseous O,S-dimethyl xanthate, CH3OC(S)SCH3, in the shallow-core S 2p region. The spectral assignment and the electronic structure are interpreted in terms of the most stable synperiplanar conformer in the Cs symmetry point group. The use of tunable synchrotron radiation allows for a selective excitation of sulfur atoms at different photon energy values, including resonance transitions and ionization around the S 2p level. The fragmentation patterns show that the title molecule is well suited as a laboratory precursor of ionic species found in the interstellar medium, especially formyl and thioformyl cations, HCO+ and HCS+, respectively. Fil: Rodriguez Pirani, Lucas Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina Fil: Canneva, Antonela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina

Come citare

Elegí el formato que necesitás y copiá la referencia al portapapeles.

APA 7

Rodriguez Pirani, L. S. E. A. (2019). Formation of HCO+ and HCS+ Ions in the Photodissociation of CH3OC(S)SCH3 under VUV Synchrotron Radiation. http://hdl.handle.net/11336/119703

MLA

Rodriguez Pirani, Lucas Sebastian et al. "Formation of HCO+ and HCS+ Ions in the Photodissociation of CH3OC(S)SCH3 under VUV Synchrotron Radiation." 2019. http://hdl.handle.net/11336/119703.

Chicago

Rodriguez Pirani, Lucas Sebastian et al. 2019. "Formation of HCO+ and HCS+ Ions in the Photodissociation of CH3OC(S)SCH3 under VUV Synchrotron Radiation.". http://hdl.handle.net/11336/119703.

Harvard

Rodriguez Pirani, L. S. E. A. 2019, Formation of HCO+ and HCS+ Ions in the Photodissociation of CH3OC(S)SCH3 under VUV Synchrotron Radiation, American Chemical Society, available at: http://hdl.handle.net/11336/119703 [Accessed 6 Aug. 2026].

Condividi e stampa

Salva la scheda, copia il link permanente o stampala in PDF.

Esporta riferimento

Esporta il record nei formati più comuni per usarlo con un gestore bibliografico.

RIS BibTeX

Dettagli della risorsa

Informazioni bibliografiche utili per verificare che sia il materiale corretto.

Titolo: Formation of HCO+ and HCS+ Ions in the Photodissociation of CH3OC(S)SCH3 under VUV Synchrotron Radiation

Autore / collaboratori: Rodriguez Pirani, Lucas Sebastian et al

Editore: American Chemical Society

Anno di pubblicazione: 2019

ISSN: 6674-6682

ISSN: 6674-6682

Lingua: Inglés

Soggetti

Esplora risorse correlate a partire da questi soggetti.

Synchrotron; Photodissociation; VUV; https://purl.org/becyt/ford/1.4; https://purl.org/becyt/ford/1