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Influence of Ge content on the activity of Ru-Ge-B/Al2O 3 catalysts for selective hydrogenation of methyl oleate to oleyl alcohol

Sánchez, María Amparo et al · Elsevier Science · 2013

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Autore / responsabile
Sánchez, María Amparo et al
Editore
Elsevier Science
Anno
2013
ISSN
0920-5861
ISSN
0920-5861
Lingua
Inglés

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The influence of Ge content on the activity and selectivity of Ru-Ge-B/Al2O3 catalysts for the hydrogenation of methyl oleate to oleyl alcohol was studied. The results of catalyst characterization by TPR and XPS show that Ge is deposited on both the metal function aggregates and on the support surface. The fraction of Ge deposited on the metal function is in strong interaction with Ru, so that its metallic activity is significantly modified. Both dehydrogenating and hydrogenolytic activities of Ru are strongly diminished by Ge addition. The Ge/Ru = 2 is the optimum ratio for oleyl alcohol production. Fil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Mazzieri, Vanina Alejandra. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina

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APA 7

Sánchez, M. A. E. A. (2013). Influence of Ge content on the activity of Ru-Ge-B/Al2O 3 catalysts for selective hydrogenation of methyl oleate to oleyl alcohol. http://hdl.handle.net/11336/78595

MLA

Sánchez, María Amparo et al. "Influence of Ge content on the activity of Ru-Ge-B/Al2O 3 catalysts for selective hydrogenation of methyl oleate to oleyl alcohol." 2013. http://hdl.handle.net/11336/78595.

Chicago

Sánchez, María Amparo et al. 2013. "Influence of Ge content on the activity of Ru-Ge-B/Al2O 3 catalysts for selective hydrogenation of methyl oleate to oleyl alcohol.". http://hdl.handle.net/11336/78595.

Harvard

Sánchez, M. A. E. A. 2013, Influence of Ge content on the activity of Ru-Ge-B/Al2O 3 catalysts for selective hydrogenation of methyl oleate to oleyl alcohol, Elsevier Science, available at: http://hdl.handle.net/11336/78595 [Accessed 7 Aug. 2026].

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Titolo
Influence of Ge content on the activity of Ru-Ge-B/Al2O 3 catalysts for selective hydrogenation of methyl oleate to oleyl alcohol
Autore / collaboratori
Sánchez, María Amparo et al
Editore
Elsevier Science
Anno di pubblicazione
2013
ISSN
0920-5861
ISSN
0920-5861
Lingua
Inglés

Soggetti

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Selective Hydrogenation Methyl Oleate Oleyl Alcohol Ru-Ge-B/Al 2o3; https://purl.org/becyt/ford/2.4; https://purl.org/becyt/ford/2
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