Hydrogen production from formic acid catalyzed by NHC–Cu complexes

Orlando Santoro et al · Beilstein-Institut · 2026

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Author / responsible party

Orlando Santoro et al

Publisher

Beilstein-Institut

Year

2026

ISSN

1860-5397

ISSN

1860-5397

Language

English

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The first NHC–Cu-catalyzed decomposition of formic acid (FA) is reported. In the presence of PhSiH3, only hydrogen is generated while CO2 is captured by a silane species. The decomposition of an equimolar mixture of FA and an amine provided an equimolar mixture of H2 and CO2. The efficiency of the catalysis showed to be strongly dependent on the nature of the amine.

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APA 7

al, O. S. E. (2026). Hydrogen production from formic acid catalyzed by NHC–Cu complexes. https://doi.org/10.3762/bjoc.22.48

MLA

al, Orlando Santoro et. "Hydrogen production from formic acid catalyzed by NHC–Cu complexes." 2026. https://doi.org/10.3762/bjoc.22.48.

Chicago

al, Orlando Santoro et. 2026. "Hydrogen production from formic acid catalyzed by NHC–Cu complexes.". https://doi.org/10.3762/bjoc.22.48.

Harvard

al, O. S. E. 2026, Hydrogen production from formic acid catalyzed by NHC–Cu complexes, Beilstein-Institut, available at: https://doi.org/10.3762/bjoc.22.48 [Accessed 7 Aug. 2026].

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Title: Hydrogen production from formic acid catalyzed by NHC–Cu complexes

Author / contributors: Orlando Santoro et al

Publisher: Beilstein-Institut

Publication year: 2026

ISSN: 1860-5397

ISSN: 1860-5397

Language: English

Subjects

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copper n-heterocyclic carbene; formic acid dehydrogenation; hydrogen storage; metal hydride; silanes