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Oxide/hydroxide films on tin. II: Characterization of the anodic growth in alkaline solutions

Brunetti, Veronica et al · Elsevier Science Sa · 2008

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Author / responsible party
Brunetti, Veronica et al
Publisher
Elsevier Science Sa
Year
2008
ISSN
0022-0728
ISSN
0022-0728
Language
English

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The anodic growth of oxide/hydroxide films formed on tin in borate solutions (pH 8.9) has been studied. At potentials more positive than -0.2 V (SHE), oxide film growth occurs by an activation-controlled ionic condition under the influence of a high electric field across the film according to an exponential law as on valve metals. Optical properties of the anodic oxide films have been obtained by "in situ" ellipsometry. Tin oxide/hydroxide films are practically transparent and highly hydrated. Electrical properties of tin oxide layers have been obtained by electrochemical impedance spectroscopy. Impedance spectra are explained in terms of a simple physical model assuming that oxide layer behaves as an inhomogeneous single-layer film. Fil: Brunetti, Veronica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Lopez Teijelo, Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina

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APA 7

Brunetti, V. E. A. (2008). Oxide/hydroxide films on tin. II: Characterization of the anodic growth in alkaline solutions. http://hdl.handle.net/11336/82625

MLA

Brunetti, Veronica et al. "Oxide/hydroxide films on tin. II: Characterization of the anodic growth in alkaline solutions." 2008. http://hdl.handle.net/11336/82625.

Chicago

Brunetti, Veronica et al. 2008. "Oxide/hydroxide films on tin. II: Characterization of the anodic growth in alkaline solutions.". http://hdl.handle.net/11336/82625.

Harvard

Brunetti, V. E. A. 2008, Oxide/hydroxide films on tin. II: Characterization of the anodic growth in alkaline solutions, Elsevier Science Sa, available at: http://hdl.handle.net/11336/82625 [Accessed 10 Aug. 2026].

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Title
Oxide/hydroxide films on tin. II: Characterization of the anodic growth in alkaline solutions
Author / contributors
Brunetti, Veronica et al
Publisher
Elsevier Science Sa
Publication year
2008
ISSN
0022-0728
ISSN
0022-0728
Language
English

Subjects

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Electrochemical Impedance Spectroscopy; Ellipsometry; High-Field Growth; Oxide/Hydroxide Layers; Tin Oxide; https://purl.org/becyt/ford/1.4; https://purl.org/becyt/ford/1
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