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Deactivation and regeneration of Pt/Al2O3 catalysts during the hydrodechlorination of carbon tetrachloride

Garetto, Teresita Francisca et al · Elsevier Science · 2009

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Deactivation and regeneration of Pt/Al2O3 catalysts during the hydrodechlorination of carbon tetrachloride were studied. The effect of reactant partial pressures and temperature on the catalyst deactivation was investigated. A deactivation model with residual activity was developed to quantify the kinetic deactivation parameters. The effect of the regeneration atmosphere was also investigated. Regeneration under air allowed for the full recovery of the catalytic performance of fresh catalysts while treatments under flowing hydrogen resulted in a superior catalytic performance, increasing both the initial and residual activities. This was ascribed to a combined effect, redispersion of the metallic phase and formation of surface defects. Fil: Garetto, Teresita Francisca. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Vignatti, Charito Ivana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina

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APA 7

Garetto, T. F. E. A. (2009). Deactivation and regeneration of Pt/Al2O3 catalysts during the hydrodechlorination of carbon tetrachloride. http://hdl.handle.net/11336/57331

MLA

Garetto, Teresita Francisca et al. "Deactivation and regeneration of Pt/Al2O3 catalysts during the hydrodechlorination of carbon tetrachloride." 2009. http://hdl.handle.net/11336/57331.

Chicago

Garetto, Teresita Francisca et al. 2009. "Deactivation and regeneration of Pt/Al2O3 catalysts during the hydrodechlorination of carbon tetrachloride.". http://hdl.handle.net/11336/57331.

Harvard

Garetto, T. F. E. A. 2009, Deactivation and regeneration of Pt/Al2O3 catalysts during the hydrodechlorination of carbon tetrachloride, Elsevier Science, available at: http://hdl.handle.net/11336/57331 [Accessed 7 Aug. 2026].

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Title
Deactivation and regeneration of Pt/Al2O3 catalysts during the hydrodechlorination of carbon tetrachloride
Author / contributors
Garetto, Teresita Francisca et al
Publisher
Elsevier Science
Publication year
2009
ISSN
0926-3373
ISSN
0926-3373
Language
English

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