News Help Institutional access
Back to results
Bibliographic record · Consultation and access
Artículo

Crystal structure refinement and vibrational analysis of Y[CO(CN)6].4H2O and its thermal decomposition products

Gil, Diego Mauricio et al · Elsevier Science · 2013

Open-access full text
Quick overview. Review the resource’s basic details, then access the content using the main button. This page shows only the information needed to identify, cite, and open the work.
Author / responsible party
Gil, Diego Mauricio et al
Publisher
Elsevier Science
Year
2013
ISSN
0166-1280
ISSN
0166-1280
Language
English

Resource access

Open the content from the main option or choose another available source.

CONICET Digital CONICET Digital OAI-PMH
Entrar por CONICET Digital
Main access

Open-access full text

Texto completo identificado como acceso abierto.
Open text

Summary

Descripción general del contenido del recurso.

Studies on Y[Co(CN)6]·4H2O by means of thermal analysis, IR and Raman spectroscopy and X-ray powder diffraction were carried out. The complex Y[Co(CN)6]·4H2O crystallizes in the orthorhombic crystal system, space group Cmcm. Y3+ ion is eight-coordinated forming bicapped distorted trigonal prism YN6O2 and Co3+ ion is octahedrally coordinated to six CN groups. The IR spectrum shows well-resolved bands in the CN stretching region due to the presence of 13C and 15N in relative natural abundance. The Raman spectrum of the complex shows two distinct set of bands of the CN stretching vibration: one is a singlet and the other is split due to the low symmetry of the Y3+ ion compared to the pentahydrate complex. The thermal decomposition was studied in order to investigate the formation of YCoO3. The crystal structure of YCoO3 was refined by means of Rietveld analysis using PXRD data. We found that it was slightly deficient in Y3+, which is in agreement with the small amount of Y2O3 found as impurity in the sample. The formula of the mixed oxide obtained by this method of synthesis is Y0.961CoO3. Fil: Gil, Diego Mauricio. Universidad Nacional de Tucuman. Facultad de Bioquimica, Quimica y Farmacia. Instituto de Quimica Inorganica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Carbonio, Raul Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Córdoba. Instituto de Investigaciones en Físicoquímica de Córdoba; Argentina

How to cite

Elegí el formato que necesitás y copiá la referencia al portapapeles.

APA 7

Gil, D. M. E. A. (2013). Crystal structure refinement and vibrational analysis of Y[CO(CN)6].4H2O and its thermal decomposition products. http://hdl.handle.net/11336/6935

MLA

Gil, Diego Mauricio et al. "Crystal structure refinement and vibrational analysis of Y[CO(CN)6].4H2O and its thermal decomposition products." 2013. http://hdl.handle.net/11336/6935.

Chicago

Gil, Diego Mauricio et al. 2013. "Crystal structure refinement and vibrational analysis of Y[CO(CN)6].4H2O and its thermal decomposition products.". http://hdl.handle.net/11336/6935.

Harvard

Gil, D. M. E. A. 2013, Crystal structure refinement and vibrational analysis of Y[CO(CN)6].4H2O and its thermal decomposition products, Elsevier Science, available at: http://hdl.handle.net/11336/6935 [Accessed 8 Aug. 2026].

Share and print

Save the record, copy its permanent link, or print it as a PDF.

Export reference

You can export the record in common formats for use in a reference manager.

RIS BibTeX

Resource details

Bibliographic information to help confirm that this is the correct material.

Title
Crystal structure refinement and vibrational analysis of Y[CO(CN)6].4H2O and its thermal decomposition products
Author / contributors
Gil, Diego Mauricio et al
Publisher
Elsevier Science
Publication year
2013
ISSN
0166-1280
ISSN
0166-1280
Language
English

Subjects

Explore related resources through these subjects.

Y[Co(Cn)6]·4h2o; Crystal Structure; Vibrational Analysis; Thermal Decomposition; https://purl.org/becyt/ford/1.4; https://purl.org/becyt/ford/1
Copied