Trends in the Exchange Current for Hydrogen Evolution

Jens K. Nørskov; Thomas Bligaard; Á. Logadóttir; John R. Kitchin; J.G. Chen; Stanislav Pandelov; Ulrich Stimming · Journal of The Electrochemical Society · 2005

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Author / responsible party

Jens K. Nørskov; Thomas Bligaard; Á. Logadóttir; John R. Kitchin; J.G. Chen; Stanislav Pandelov; Ulrich Stimming

Publisher

Journal of The Electrochemical Society

Year

2005

Language

English

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A density functional theory database of hydrogen chemisorption energies on close packed surfaces of a number of transition and noble metals is presented. The bond energies are used to understand the trends in the exchange current for hydrogen evolution. A volcano curve is obtained when measured exchange currents are plotted as a function of the calculated hydrogen adsorption energies and a simple kinetic model is developed to understand the origin of the volcano. The volcano curve is also consistent with Pt being the most efficient electrocatalyst for hydrogen evolution.

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APA 7

Nørskov, J. K, Bligaard, T, Logadóttir, Á, Kitchin, J. R, Chen, J, Pandelov, S, & Stimming, U. (2005). Trends in the Exchange Current for Hydrogen Evolution. https://doi.org/10.1149/1.1856988

MLA

Nørskov, Jens K, et al. "Trends in the Exchange Current for Hydrogen Evolution." 2005. https://doi.org/10.1149/1.1856988.

Chicago

Nørskov, Jens K, Thomas Bligaard, Á. Logadóttir, John R. Kitchin, J.G. Chen, Stanislav Pandelov, and Ulrich Stimming. 2005. "Trends in the Exchange Current for Hydrogen Evolution.". https://doi.org/10.1149/1.1856988.

Harvard

Nørskov, J. K. et al. 2005, Trends in the Exchange Current for Hydrogen Evolution, Journal of The Electrochemical Society, available at: https://doi.org/10.1149/1.1856988 [Accessed 9 Aug. 2026].

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Title: Trends in the Exchange Current for Hydrogen Evolution

Author / contributors: Jens K. Nørskov; Thomas Bligaard; Á. Logadóttir; John R. Kitchin; J.G. Chen; Stanislav Pandelov; Ulrich Stimming

Publisher: Journal of The Electrochemical Society

Publication year: 2005

Language: English

Subjects

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Chemisorption; Hydrogen; Electrocatalyst; Density functional theory; Current (fluid); Chemistry; Exchange current density; Adsorption; Kinetic energy; Chemical physics; Electrochemistry; Atomic physics