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Anionic ring opening polymerization of ε-caprolactone initiated by lithium silanolates

Satti, Angel Jose et al · Csiro Publishing · 2016

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Author / responsible party
Satti, Angel Jose et al
Publisher
Csiro Publishing
Year
2016
ISSN
0004-9425
ISSN
0004-9425
Language
English

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Ring-opening homo- and co-polymerization reactions of ε-caprolactone were performed by employing anionic polymerization (high vacuum techniques) and lithium silanolates (LS) as initiators. LS were obtained by reaction between hexamethyl(cyclotrisiloxane) and sec-Bu–Li+, or from living poly(dimethylsiloxanyl)lithium chains. The results indicated that LS are efficient initiators for the ring-opening polymerization of ε-caprolactone, providing the respective homogeneous polymers in good yields. Fil: Satti, Angel Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina Fil: de Freitas, Augusto G. O.. Universidade Federal de Santa Maria. Departamento de Química; Brasil

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APA 7

Satti, A. J. E. A. (2016). Anionic ring opening polymerization of ε-caprolactone initiated by lithium silanolates. http://hdl.handle.net/11336/27087

MLA

Satti, Angel Jose et al. "Anionic ring opening polymerization of ε-caprolactone initiated by lithium silanolates." 2016. http://hdl.handle.net/11336/27087.

Chicago

Satti, Angel Jose et al. 2016. "Anionic ring opening polymerization of ε-caprolactone initiated by lithium silanolates.". http://hdl.handle.net/11336/27087.

Harvard

Satti, A. J. E. A. 2016, Anionic ring opening polymerization of ε-caprolactone initiated by lithium silanolates, Csiro Publishing, available at: http://hdl.handle.net/11336/27087 [Accessed 9 Aug. 2026].

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Title
Anionic ring opening polymerization of ε-caprolactone initiated by lithium silanolates
Author / contributors
Satti, Angel Jose et al
Publisher
Csiro Publishing
Publication year
2016
ISSN
0004-9425
ISSN
0004-9425
Language
English

Subjects

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Lithium; Silanolates; Caprolactone; Polymerization; https://purl.org/becyt/ford/2.4; https://purl.org/becyt/ford/2
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