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Chemosensing of nitroaromatics with a new segmented conjugated quaterphenylene polymer

del Rosso, Pablo Gabriel et al · Pergamon-Elsevier Science Ltd · 2011

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A new approach for introducing porosity in fluorescent polymer films to increase sensing performance is presented. A novel segmented conjugated polymer composed of p-quaterphenylene segments tethered by their meta positions along the polymer main chain by 2,2-isopropylene spacers was synthesized. The bent nature of its microstructure generates amorphous morphologies that let analytes diffuse rapidly within the films. Fluorescence quenching studies with polymer films and methanol solutions of nitroaromatics showed high sensitivity, fast response and reversibility of the fluorescence quenching. Thus, half of the maximum quench (Q 50%) occurred with nitrobenzene at the micromolar range in less than 1 min in a reversible manner. © 2011 Elsevier Ltd. All rights reserved. Fil: del Rosso, Pablo Gabriel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina Fil: Almassio, Marcela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Instituto de Química del Sur. Universidad Nacional del Sur. Departamento de Química. Instituto de Química del Sur; Argentina

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APA 7

del Rosso, P. G. E. A. (2011). Chemosensing of nitroaromatics with a new segmented conjugated quaterphenylene polymer. http://hdl.handle.net/11336/64073

MLA

del Rosso, Pablo Gabriel et al. "Chemosensing of nitroaromatics with a new segmented conjugated quaterphenylene polymer." 2011. http://hdl.handle.net/11336/64073.

Chicago

del Rosso, Pablo Gabriel et al. 2011. "Chemosensing of nitroaromatics with a new segmented conjugated quaterphenylene polymer.". http://hdl.handle.net/11336/64073.

Harvard

del Rosso, P. G. E. A. 2011, Chemosensing of nitroaromatics with a new segmented conjugated quaterphenylene polymer, Pergamon-Elsevier Science Ltd, available at: http://hdl.handle.net/11336/64073 [Accessed 8 Aug. 2026].

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Title
Chemosensing of nitroaromatics with a new segmented conjugated quaterphenylene polymer
Author / contributors
del Rosso, Pablo Gabriel et al
Publisher
Pergamon-Elsevier Science Ltd
Publication year
2011
ISSN
4911-4915
ISSN
4911-4915
Language
English

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