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Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene

Zelin, Juan et al · Elsevier · 2015

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Author / responsible party
Zelin, Juan et al
Publisher
Elsevier
Year
2015
ISSN
0926-860X
ISSN
0926-860X
Language
English

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Abstract The activity and selectivity of silica-supported Hoveyda-Grubbs (HG) complex for the cross-metathesis of methyl oleate with 1-hexene to obtain 1-decene, methyl 9-tetradecenoate, 5-tetradecene and methyl 9-decenoate were studied in a batch reactor. The HG complex loading was varied between 0.87 and 11.6 wt%. Competitive secondary reactions were the self-metathesis of methyl oleate and the self-metathesis of 1-hexene. The yield to cross-metathesis products (ηC-M) was 47% when a 1-hexene/methyl oleate reactant ratio (RC6/MO) of one was employed. The ηC-M value increased with increasing 1-hexene initial concentration, reaching 87% for RC6/MO = 7. The selectivity to terminal olefins also increased at the expense of internal olefins among the cross-metathesis products when the concentration of 1-hexene was increased. Fil: Zelin, Juan. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina Fil: Nieres, Pablo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina

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APA 7

Zelin, J. E. A. (2015). Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene. http://hdl.handle.net/11336/36653

MLA

Zelin, Juan et al. "Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene." 2015. http://hdl.handle.net/11336/36653.

Chicago

Zelin, Juan et al. 2015. "Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene.". http://hdl.handle.net/11336/36653.

Harvard

Zelin, J. E. A. 2015, Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene, Elsevier, available at: http://hdl.handle.net/11336/36653 [Accessed 7 Aug. 2026].

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Title
Valorisation of vegetable oils via metathesis reactions on solid catalysts: Cross-metathesis of methyl oleate with 1-hexene
Author / contributors
Zelin, Juan et al
Publisher
Elsevier
Publication year
2015
ISSN
0926-860X
ISSN
0926-860X
Language
English

Subjects

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1-Hexene; Cross-Metathesis; Fame; Hoveyda-Grubbs Catalysts ; Methyl Oleate; Oleochemistry; https://purl.org/becyt/ford/2.4; https://purl.org/becyt/ford/2
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