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On the Role of Mesoentropy in Thermodynamics of First Order Phase Transformations in Alloys

A. Shirinyan · Vasyl Stefanyk Carpathian National University · 2016

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Author / responsible party
A. Shirinyan
Publisher
Vasyl Stefanyk Carpathian National University
Year
2016
ISSN
1729-4428
ISSN
1729-4428
Language
English

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<blockquote><blockquote>A thermodynamics of a new phase formation in a binary alloy, taking into account the chemical depletion and the size distribution of new phase nuclei giving the energy input at high temperatures, is considered. It is shown the principal possibility of obtaining of the size distribution function for nuclei in the framework of a general variation procedure for the Gibbs free energy functional. The ‘chemical depletion’ related to the difference of compositions of the new phase embryo and the solution of the solid metastable alloy is discussed. The role of the ‘mesoentropy’ for the determination of whole energy of first order phase transformation is manifested. <br /><strong>Keywords:</strong> new phase embryo, Gibbs potential, chemical depletion, mesoentropy, size distribution, nucleation sites, variational procedure.</blockquote></blockquote>

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APA 7

Shirinyan, A. (2016). On the Role of Mesoentropy in Thermodynamics of First Order Phase Transformations in Alloys. https://doi.org/10.15330/pcss.16.1.20-27

MLA

Shirinyan, A. "On the Role of Mesoentropy in Thermodynamics of First Order Phase Transformations in Alloys." 2016. https://doi.org/10.15330/pcss.16.1.20-27.

Chicago

Shirinyan, A. 2016. "On the Role of Mesoentropy in Thermodynamics of First Order Phase Transformations in Alloys.". https://doi.org/10.15330/pcss.16.1.20-27.

Harvard

Shirinyan, A. 2016, On the Role of Mesoentropy in Thermodynamics of First Order Phase Transformations in Alloys, Vasyl Stefanyk Carpathian National University, available at: https://doi.org/10.15330/pcss.16.1.20-27 [Accessed 9 Aug. 2026].

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Title
On the Role of Mesoentropy in Thermodynamics of First Order Phase Transformations in Alloys
Author / contributors
A. Shirinyan
Publisher
Vasyl Stefanyk Carpathian National University
Publication year
2016
ISSN
1729-4428
ISSN
1729-4428
Language
English
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